Initiation Mechanism of Radiation-Induced Ionic Polymerization of Isobutene Studied by Ion Cyclotron Resonance

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Photo and Radiation Induced Ionic Polymerization

Photo-induced cationic polymerizations of styrene and x-methylstyrene, which are weak electron donors and contain no hetero atom, were carried out in the presence of electron acceptors such as tetracyanobenzene and pyromellitic dianhydride to elucidate the polymerization mechanism initiated through an excited charge transfer interaction. Cyclohexene oxide was also polymerized by photo-illuminat...

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ژورنال

عنوان ژورنال: Bulletin of the Chemical Society of Japan

سال: 1971

ISSN: 0009-2673,1348-0634

DOI: 10.1246/bcsj.44.2261